It is an orange solid with a camphorlike odor, that sublimes above room temperature, and is soluble in most organic solvents. This product has been classified in accordance with the hazard criteria of the controlled products regulations and the msds contains all of the information required by those regulations. Methylene chloride revision date 28nov2019 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. The compound is soluble in common organic solvents and stable towards acids and bases.
Ferrocene c5h5fec5h5 or fec10h10 or c10h10fe cid 7611 structure, chemical names, physical and. Safety data sheet according to 29cfr19101200 and ghs rev. To have access to all the functionalities of this website, including msdss in your preferred language please select your country. Page 4 of msds hexane protective measures avoid contact with spilled material. The general population may be exposed by vapors, ingestion, dermal or eye contact.
It is an unusually stable orange crystalline solid with a formula of fec 10 h 10 heat of decomposition 465. In case of contact, flush skin with plenty of water. Cyclic voltammetry and scanning electrochemical microscopy of. The heat of solution of ferrocene in methanol has been reported to be 17. Chitosan, ferrocene methanol meohfc, horseradish peroxidase, and phenyl methyl sulfonyl fluoride. If necessary use trained response staff or contractor. The molecule consists of two cyclopentadienyl rings bound on opposite sides of a central iron atom. Absorb with a noncombustible absorbent material such as sand or earth and containerize for disposal. A multilinear quantitative structure property relationship qspr model based on theoretical descriptors and a new linear solvation energy relationship lser model based on empirical scales of solvents are. Dec 04, 2015 the solubility of ferrocene in various organic solvents is important because of its application in chemical process and its role as a standard electrochemical probe in nonaqueous systems. Barda a department of chemistry and biochemistry, the university of texas at austin, austin, tx 78712, usa. Ferrocene methanol was dissolved by immersion of the corresponding solution in an ultrasonic bath for approximately 5 min.
Persistence and degradability iodine 7553 56 2 persistence and degradability not established. C5h52, is of historical importance since its discovery and structural characterisation in the early 1950s sparked extensive research into. Warn or evacuate occupants in surrou nding and downwind areas if required due to toxicity or flammability of the material. Precautionary statements p280 wear protective gloves protective clothing eye protection face protection. Safety data sheet according to federal register vol. Page 1 of 8 ferrocene cas no 102545 material safety data sheet sds msds section 1. Ferrocene is an organometallic compound with the formula fec 5 h 5 2. Vapor phase benzophenone is degraded in the ambient atmosphere by reaction with. P271 use only outdoors or in a wellventilated area. Mobility in soil no additional information available 12. Identification of the substancemixture and of the companyundertaking. In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes.
The number of electrons in each of irons shells is 2, 8, 14, 2 and its electron configuration is ar 3d 6 4s 2. May cause eye, skin, and respiratory tract irritation. Safety data sheet 1,1bisdiphenylphosphinoferrocene. Characterization of pyranose oxidase variants for bioelectrocatalytic. Ferrocene vapors were produced by heating ferrocene aerosols.
Workers that use methanol may breathe in mists or have direct skin contact. Male and female f344rats and b6c3f1mice were exposed in whole body exposure chambers to filtered air or 2. Butyl alcohols have produced few cases of poisoning in industry because of their low volatility. Methanol is an ingredient in many products for car and home maintenance and arts and crafts. Based on this vapor pressure value, benzophenone should exist almost entirely in the vapor phase in the ambient atmosphere. It is used in the synthesis of ferrocenylmethoxyisatins, potent antiproliferative agents. C5h52, is of historical importance since its discovery and structural characterisation in the early 1950s sparked extensive research into the chemistry.
In general, there is a considerable lack of data corresponding to thermodynamics of dissolution of ferrocene in mixed solvents, especially commercially available solvents. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ferrocene exhibits the properties of a typical aromatic molecule. Exposures were for 5 days per week for 2 weeks, with 2 or 3 additional days of exposure to fulfill experimental protocol. Absorb spill using an absorbent, noncombustible material such as earth, sand, or vermiculite. The diffusion of ferrocene methanol in supercooled aqueous solutions containing sucrose has been studied, using disk and cylindrical microelectrodes, over a wide viscosity range. Cyclic voltammetry and scanning electrochemical microscopy of ferrocenemethanol at monolayer and bilayermodi. Carbon introduction the archetypal organometallic compound ferrocene, fe. Diffusion of ferrocene methanol in supercooled aqueous. On the solubility of ferrocene in nonaqueous solvents.
Pdf octane rating of gasoline and octane booster additives. Bioaccumulative potential iodine 7553 56 2 log pow 2. Ferrocene is an ironbased additive discovered in the early 1950s. P270 do not eat, drink or smoke when using this product. Page 1 of 8 ferrocene cas no 102545 material safety data sheet sdsmsds section 1. Page 1 of 10 material safety data sheet methanol product name methanol ch 3oh synonyms alcohol, methyl hydroxide, methyl hydrate, wood alcohol, wood spirit product use solvent, fuel, feedstock company identification methanol holdings trinidad limited atlantic avenue, point lisas industrial estate. Show this safety data sheet to the doctor in attendance. A vapor suppressing foam may be used to reduce vapors. Get medical aid if irritation develops and persists. Octane rating of gasoline and octane booster additives article pdf available in petroleum science and technology 3311 june 2015 with 16,944 reads how we measure reads. Fcmeoh can be employed in the preparation of ferrocenecarbohydrate conjugates for biosensing applications. Difficult breathing, coughing, headache, dizziness, and drowsiness may occur.
Lcms grade methanol, part number 51906896 section 2. Sigmaaldrich corporation and its affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. The hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The mixture was purged with nitrogen for approximately one hour and heated, with occasional stirring, until complete dissolution of the sugar. Fcmeoh can be employed in the preparation of ferrocene carbohydrate conjugates for biosensing applications. Thermodynamics of dissolution of ferrocene in commercial.
Cyclic voltammetric studies of ferrocene in nonaqueous solvents in the. Investigating the synthesis and reactivity of ferrocene. This procedure resulted in bubble free samples with the desired water content. Section 1 chemical product and company identification. Ferrocene is an organometallic compound with the formula fec 5h 5 2. Firstaid measures general advice show this safety data sheet to the doctor in attendance. Skin contact wash off immediately with plenty of water for at least 15 minutes. Keep in a tightly closed container, stored in a cooled, dry, ventilated area.
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